Direct Solar Conversion of Biogas to Hydrogen and Solid Carbon: A Novel, Zero-Carbon Process

Green hydrogen production through solar heating

The Regents of the University of California on behalf of the Los Angeles Campus

Recipient

Los Angeles, CA

Recipient Location

24th

Senate District

51st

Assembly District

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$79,059

Amount Spent

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Active

Project Status

Project Update

The project team has finished the engineering design and is currently assembling equipment to build a field-scale demo of a photo-thermal reactor and testing its performance in laboratory experiments. The project team is discussing site plans and requirements with project partners and stakeholders to plan and scope the field demonstration.

The Issue

Hydrogen is overwhelmingly produced through steam methane reforming (SMR), a process that converts methane to hydrogen while yielding significant carbon dioxide (CO2) emissions. While electrolysis of water using renewable electricity is currently the leading research technology for producing low-carbon hydrogen and is commercially available, this process cannot cost-effectively convert biogas or other sources of biogenic fuel into hydrogen.

Project Innovation

This project advances a novel technology that uses solar energy directly to convert hydrocarbon gas from any source, including biogas, into clean hydrogen and a high-value form of solid graphitic carbon, resulting in zero greenhouse gas (GHG) emissions. When deployed with renewably sourced methane, the technology can produce hydrogen that is strongly carbon negative. The technology represents a game-changing breakthrough that, when commercialized, will in and of itself drive state and national leadership in zero-carbon technology development, domestic jobs growth, and the production of clean hydrogen at a very low cost.

Project Goals

Advance solar radiation-based biogas-to-high-purity low-carbon hydrogen production technology from TRL 3 to TRL 5.
Scale-up the current laboratory system to demonstrate biogas-to-hydrogen production at field scale on sun.
Optimize system operation, diagnostics, and hardware to meet hydrogen cost targets of $2 per kg of H2 at commercial scale.
Produce an average rate of 1 kg of hydrogen per day over a series of at least 10 testing cycles.
Achieve maximum hydrogen purity for end-use operations.
Demonstrate the project in a natural gas Investor Owned Utility service territory (Southern California Gas Company).
Generate environmental and economic data needed to support greater adoption and commercialization.

Project Benefits

This project has the potential to lower costs for renewable hydrogen production by developing a new, low-carbon, low-cost hydrogen production technology capable of converting renewable biogas to hydrogen while further offsetting production costs through co-product sales of graphitic carbon. Hydrogen generated by the system can be subsequently used for a variety of end uses, including transportation, high-temperature heating for industrial processes, and electricity generation in fuel cells or otherwise to support high-efficiency and reduced-cost electricity production based on stored renewable energy.

Lower Costs

Affordability

The project is developing a low-cost hydrogen production technology that converts renewable biogas to hydrogen and offsets production costs through graphitic carbon co-production.

Environmental & Public Health

Environmental Sustainability

UCLA has developed a system that replaces methane-derived heat with concentrated solar energy to increase the reactor's temperature above 1000°C. When fully demonstrated, UCLA's technology can enable renewable biogas to be converted directly to zero-emission hydrogen.

Key Project Members

Project Member

Timothy Fisher

Project Manager
UCLA Nanoscale Transport Research Group

Contact the Team

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